Studies on chromium(III) removal from aqueous solutions by sorption on Sphagnum moss peat
نویسندگان
چکیده
Batch sorption experiments were performed for the removal of chromium(III) ions from aqueous solutions using Romanian Sphagnum moss peat (untreated and treated with NaCl solution) as sorbent. In order to establish the best conditions for the sorption of chromium(III), the influence of initial pH, contact time, peat dose and metal ion concentration was investigated. The Freundlich, Langmuir and Dubinin–Radushkevich models were applied to describe the sorption isotherms and to calculate its constants. The experimental data fitted well to the Langmuir model with a maximum sorption capacity of 18.6 mg Cr(III)/g of peat. The mean free energy of sorption suggests that the binding of Cr(III) on peat occurred through an ion exchange mechanism. The kinetic data evaluated by pseudo-first order and pseudo-second order kinetic models showed that the sorption of chromium onto the peat followed a pseudo-second order rate equation. The chromium(III) could be easily eluted from the loaded peat using 0.10 M HCl and the peat may be reused in several sorption/desorption cycles. The experimental results indicated the potential of Sphagnum moss peat for removal of Cr(III) from wastewaters.
منابع مشابه
Study of the Sorption of Divalent Metal Ions on to Peat
A pseudo-second order rate equation describing the kinetics of sorption of divalent metal ions on to sphagnum moss peat at various initial metal ion concentrations and peat doses has been developed. The sorption kinetics were followed based on the concentrations of metal sorbed at various time intervals. Results show that chemical sorption processes might be rate-limiting for the sorption of di...
متن کاملRemoval of hexavalent chromium from aqueous solution using canola biomass: Isotherms and kinetics studies
The removing of hexavalent chromium from wastewater or decreasing its chromium (VI) content up to the permitted levels is important due to its non-biodegradation, bioaccumulation, and cancer-causing and toxic effects. In the present study, biosorption of Cr (VI) from aqueous solutions using canola was investigated. The various physicochemical parameters such as pH, initial Cr (VI) ion concentra...
متن کاملStudies on removal of Zinc and Chromium from aqueous solutions using water Hyacinth
Phytoremediation is an eco-friendly method for removal of pollutants, which can be relied upon as a sustainable technology, if implemented under optimum conditions of plant growth. The effectiveness of water hyacinth, a topical weed, for the removal of Zinc (Zn) and Chromium (Cr) ions from aqueous solutions has been presented in this article. The potential of this plant in removing metals by ph...
متن کاملStudies on removal of Zinc and Chromium from aqueous solutions using water Hyacinth
Phytoremediation is an eco-friendly method for removal of pollutants, which can be relied upon as a sustainable technology, if implemented under optimum conditions of plant growth. The effectiveness of water hyacinth, a topical weed, for the removal of Zinc (Zn) and Chromium (Cr) ions from aqueous solutions has been presented in this article. The potential of this plant in removing metals by ph...
متن کاملFixed Bed Column Study on the Removal of Chromium (iii) Ions from Aqueous Solutions by Using Hemp Fibers with Improved Sorption Performance
Cr (III) removal from aqueous solutions by sorption in a fixed bed column filled with alizarin S impregnated hemp fibers has been studied. The effect of the initial metal ion concentration on the Cr (III) sorption process was investigated and the experimental breakthrough curves were obtained. The breakthrough time and saturation time decreased from 110 min to 80 min and from 300 min to 160 min...
متن کامل